Catalysis of Organic Reactions (Innbundet (stive permer))

This volume compiles 63 peer-reviewed scientific papers documenting the latest developments in the application of homogeneous, heterogeneous, and immobilized homogenous catalysts used in organic synthesis. "Catalysis of Organic Reactions" consists of primary research articles accompanied by experimental sections that emphasize chemical processes with actual and potential applications in industry.Each chapter represents current and outstanding research by recognized leaders in the field. Organized into five major symposia, topics include selective homogeneous and heterogeneous catalysis for the synthesis of fine chemical and pharmaceuticals, solid acid catalysis, selective oxidation, amination, chiral catalysis, combinatorial technologies, nanoparticles, environmentally friendly catalysis, and more. The collection also presents the award-winning research of Jean Lessard, concerning the scope and limitations of electrocatalytic hydrogenation of organic compounds at Raney Metal Electrodes, and Richard Larock, relating to palladium-catalyzed annulation and migration reactions.These proceedings are of interest to the chemical scientists and engineers whose special interest is to apply homogenous and heterogeneous catalysts in organic synthesis of pharmaceutical, fine, and commodity chemicals.

Preface Symposium on Catalytic Hydrogenation Hydrogenation on Raney-Type Catalysts 2004 Murray Raney Lecture, Electrocatalytic Hydrogenation of Organic Compounds at Raney Metal Electrodes: Scope and Limitations Low Pressure Slurry Hydrogenation Process for the Production of Dimethylaminopropylamine Using Sponge Nickel Catalyst The Conversion of Ethanolamine to Glycine Salt Over Skeletal Copper Catalysts Hydrogenation Catalysis in a Nylon Recycle Process Hydrogenation of Dodecanenitrile Over Raney Type and Supported Group VIII. Effect of Metal on Selectivity Anchored and Supported Hydrogenation Catalysts Highly Efficient Catalysts Supported on Carbon Cloths for Carbohydrate Hydrogenation Anchored Wilkinson's Catalyst Carbon Supported Anchored Homogeneous Catalyst Catalytic Hydrogenation of Cinnamaldehyde on Pt/Carbon Catalysts: The Effects of Metal Location, and Dispersion on Activity and Selectivity Para-substituted Aniline Hydrogenation Over Rhodium Catalysts: Metal Particle Size and Catalyst Pore Size Effects Reductive Alkylation During Nitrobenzene Hydrogenation Over Copper/Silica Hydrogenolysis of Butyl Acetate to Butanol Over Naphtha Reforming Type Catalysts in Conventional and High Throughput Slurry Phase Reactors New Ways for the Full Hydrogenation of Quinoline in Mild Conditions Some Recent Developments of Heterogeneous Hydrogenation Catalysts for Organic Synthesis Hydrogenation of Interesting Substrates and Renewable Sources Hydrogenation of Nitrile Butadiene Rubber Catalyzed by [Ir(COD)py(PCy3)]PF6 Catalytic Hydrogenation and Hydrogenolysis of Lignin Model Compounds Using In-Situ, Water-Soluble Ru/P(CH2OH)3 Systems Catalytic Preparation of Pyrrolidones from Renewable Resources Hydrogenation of Glutamic Acid to Value Added Products Catalytic Hydrogenolysis of 5-Carbon Sugar Alcohols Symposium on Novel Concepts and Approaches to Catalysis of Organic Reactions Featured Technology Area: Combinatorial and Parallel Methods in Catalyst Design, Optimization and Utilization Combinatorial Approaches for New Catalysts Discovery: The First Homogeneous Catalysts Derived from Combinatorial Technologies for a Variety of Cross-Coupling Reactions High Throughput Experiments in Design and Optimization of Catalytic Package for Direct Diphenylcarbonate Synthesis Rapid Optimization of Hydrogenation Process Variables by Combining Experimental Design and Parallel Reactors Design and Parallel synthesis of New Oxidative Dehydrogenation Catalysts Nanocluster-based Cross-coupling Catalysts: A High-Throughput Approach General papers Do You Need A Transition Metal for Biaryl Synthesis? Enzyme-like Acceleration in Catalytic Anti-Markovnikov Hydration of Alkynes to Aldehydes An Enzyme-like Mechanism Involving Bifunctional Ru Catalysts Activation of Dendrimer Encapsulated Pt Nanoparticles for Heterogeneous Catalysts Avada-A New Green Process for the Production of Ethyl Acetate A Catalytic Distillation Process for the One Step Synthesis of Methyl Isobutyl Ketone from Acetone: Liquid Phase Kinetics of the Hydrogenation of Mesityl Oxide A Strategy for the Preparation of Isolated Organometallic Catalysts on Silica Supports - Towards Single-Site Solid Catalysts Ring Opening of Naphthenes for Clean Diesel Fuel Production The Use of Copper Catalysts in the Hydrogen Transfer Reduction of 4-Tert-butylcyclohexanone The Effect of Ultrasound on the Isomerization versus Reduction Reaction Pathways in the Hydrogenation of 3-Buten-2-ol and 1,4-Pentadien-3-ol on Pd-Black Lessons Learned, Batch Processing Scaleup from Laboratory to Plant Symposium on Acid-Base Catalysis Improved Solid-Acid Catalysis for Sustainable, High 2-Phenyl, LAB Production Recent Advances in Thermally Stable Resins for Olefin Hydration Enhancement of Regioselectivity in the Gas-phase Methylation of m-Cresol with Multifunctional Heterogeneous Catalysts Hydroxymethylation of 2-Methoxyphenol with Formaldehyde to Yield Vanillic Alcohols: A Comparison Between Homogeneous and Heterogeneous Acid Catalysis The Aldol Condensation of Acetone Over a CsOH/SiO2 Solid Base Catalyst Solid Acid Catalysed Esterification of Amino Acids One Pot Transformation of Geraniol into Citronellol and Menthol Over Cu/Al2O3 Investigation of Chlorine Substitution Effects in the Claisen-Schmidt Condensation of 2-hydroxyacetophenone with Chlorobenzaldehydes Over MgO Symposium on Catalytic Oxidation The Effect of Single Metal Variation in Mo-V-Nb-W/Al2O3 System on Propane Selective Oxidation Partial Oxidation of Propylene Over Supported Rhodium Catalysts The Effect of Promoters on the Platinum Group Metal Catalysed Selective Oxidation of Alcohols to Carbonyls or Acids Synergistic Effect of Vanadium on the Activity of Titanium-Modified Silica Catalysts for Olefin Epoxidation Aerobic Formaldehyde Oxidation Under Mild Conditions Mediated by Ce-Containing Polyoxometalates Symposium on Catalysis in Organic Synthesis General Papers 2004 Paul N. Rylander Award: Palladium-Catalyzed Annulation and Migration Reactions New Palladium-catalysed Processes for the Synthesis of Selectively Substituted Aromatics O-Acylphosphites: New and Promising Ligands for Isomerizing Hydroformylation The Synthesis of Carbamate From the Reductive Carbonylation of Nitrobenzene Over Pd-based Catalysts Microwave Synthesis in the Suzuki-Cross Coupling Reaction with Heterogenous Pd/C Catalysts Deprotection Improved Catalyst for the Removal of Carbobenzyloxy Protective Groups The Effect of N-Containing Modifiers on the Deprotection of Carbobenzyloxy Protected Amino Acids Selective Debenzylation in the Presence of Aromatic Chlorine on Pd/C Catalysts: Effects of Catalyst Types and Reaction Kinetics Asymmetric Catalysis A Comparison Between the Homogeneous and the Anchored Rhodium Skewphos Catalyst Synthesis and Characterization of Dipeptido Phosphinite Ligands for Late Transition Metal Complexations and Their Potential as Catalysts Enantioselective Hydrogenations of Exo- and Endocyclic C=C double Bond with Highly Mesoporous Carbon Supported Pd Influence of Achiral Tertiary Amines on the Enantioselective Hydrogenation of a,b-diketones Over Cinchonidine-Pt/Al2O3 Catalyst Enantioselective Hydrogenation of Diketones on Pt Supported Catalysts Enantioselective Hydrogenation of a?b-Unsaturated Acids or Esters The Effects of Pt/Al2O3 Structure and Stability on the O-Methyl-10,11-dihydrocinchonidine Modified Enantioselective Hydrogenation of Activated Ketones Author Index Keyword Index