Volume 4 focuses on additions and the resulting substitutions at
carbon-carbon -bonds. Part 1 includes processes generally considered
as simple polar reactions, reactive electrophiles and nucleophiles
adding to alkenes and alkynes. A major topic is Michael-type addition
to electron deficient -bonds, featured in the first six chapters. In
part 2 are collected the four general processes leading to
nucleophilic aromatic substitution, including radical chain processes
and transition metal activation through to -complexation.
Metal-activated addition (generally by nucleophiles) to alkenes and
polyenes is presented in part 3, including allylic alkylation
catalyzed by palladium. The coverage of nonpolar additions in part 4
includes radical additions, organometal addition (Heck reaction),
carbene addition, and 1,3-dipolar cycloadditions.
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Produktdetaljer
ISBN
9780080912479
Publisert
2018
Utgiver
Vendor
Pergamon
Språk
Product language
Engelsk
Format
Product format
Digital bok