A short historical introduction serves to introduce many common stereochemical terms used throughout the book. Chapter two is an account of the structures of simple unstrained organic molecules followed by examples of strained molecules. The third chapter deals with conformational analysis of acyclic and carbocyclic molecules, ending with a short exposition of molecular mechanics. Chapter four is about stereoisomerism in molecules and compounds. A full description of enantiomerism and diastereomerism is followed by an explanation of the nomenclature for absolute and relative configurations of molecules and for topism. A short chapter describes racemates, their resolution, and methods for determining enantiomeric purity. The book concludes with a survey of stereoselective and stereospecific reactions, including the use of chiral catalysts and auxiliaries, rules for predicting stereoselectivity, and double asymmetric synthesis.
Les mer
This book is an account for students of how the three-dimensional shapes of molecules influence their chemical and physical properties. It begins with the structures of molecules and then describes how such structures can be changed.
Les mer
Introduction ; Developments of methods and concepts in organic stereochemistry ; Organic molecules ; Shapes, Sizes and Strain problems ; The changing shapes of organic molecules ; Problems ; Stereoisomerism in molecules and compounds ; Problems ; Racemates and resolution ; Stereospecific and stereoselective reactions ; Problems ; Answers and hints
Les mer
Progressive approach from simple structures to more complex reactions very much aimed at students Clear explanation of modern nomenclature Provides good physical basis to stereochemistry
Dr Michael J T Robinson MA Dphil, Magdalen College, University of Oxford, Oxford OX1 4AU
Progressive approach from simple structures to more complex reactions very much aimed at students Clear explanation of modern nomenclature Provides good physical basis to stereochemistry

Produktdetaljer

ISBN
9780198792758
Publisert
2000
Utgiver
Vendor
Oxford University Press
Vekt
210 gr
Høyde
246 mm
Bredde
188 mm
Dybde
6 mm
Aldersnivå
U, 05
Språk
Product language
Engelsk
Format
Product format
Heftet
Antall sider
96

Forfatter

Biographical note

Dr Michael J T Robinson MA Dphil, Magdalen College, University of Oxford, Oxford OX1 4AU