This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.
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This volume is the first student text on the subject and covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself.
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History of Organometallic Chemistry.- History of Organometallic Chemistry.- Structures of the Transition-Metal Complexes.- Monometallic Transition-Metal Complexes.- Bimetallic Transition-Metal Complexes and Clusters.- The Stoichiometric Reactions of Transition-Metal Complexes.- Redox Reactions, Oxidative Addition and ?-Bond Metathesis.- Reactions of Nucleophiles and Electrophiles with Complexes.- Ligand Substitution Reactions.- Insertion and Extrusion Reactions.- The Main Families of Organometallic Complexes.- Metal Carbonyls and Complexes of Other Monohapto L Ligands.- Metal-Alkyl and -Hydride Complexes and Other Complexes of Monohapto X Ligands.- Metal-Carbene and -Carbyne Complexes and Multiple Bonds with Transition Metals.- ? Complexes of Mono- and Polyenes and Enyls.- Metallocenes and Sandwich Complexes.- Ionic and Polar Metal-Carbon Bonds: Alkali and Rare-Earth Complexes.- Covalent Chemistry of the Organoelements of Frontier (11, 12) and Main (13–16) Groups.- Catalysis.- to Catalysis.- Hydrogenation and Hydroelementation of Alkenes.- Transformations of Alkenes and Alkynes.- Oxidation of Olefins.- C-H Activation and Functionalization of Alkanes and Arenes.- Carbonylation and Carboxylation Reactions.- Bio-Organometallic Chemistry: Enzymatic Catalysis.- Heterogeneous Catalysis.- Applications in Organic Synthesis.- Organometallic Complexes in Organic Synthesis Examples of Applications.
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Aus den Rezensionen: "Das erfolgreiche franzosische Lehrbuch 'Chimie Organometallique' liegt nun uberarbeitet in englischer Ubersetzung vor. Es soll als Begleitung zur ersten Vorlesung in metallorganischer Chemie dienen und fortgeschrittenen Studenten durch umfangreiche Literaturzitate den Einstieg in spezielle Themen erleichtern. Deshalb geht der Autor deutlich uber die reinen Grundlagen hinaus und versucht, dem Leser die metallorganische Chemie in ihrer ganzen Breite (und daruber hinaus) mit aktuellen Entwicklungen vorzustellen und schmackhaft zu machen. ... Gliederung und Aufbau sind fur ein Lehrbuch sehr gut gewahlt. Der Stoffumfang ist keinesfalls zu knapp und die detaillierte Beschreibung der ersten beiden Teile wird einem guten Lehrbuch voll gerecht ..." (Doris Kunz, in: Nachrichten aus der Chemie, 2008. Vol. 56, Issue 4, S. 469)
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First book for students Includes exercises and summaries after each chapter Organometallic chemistry is covered in the broadest possible way Includes supplementary material: sn.pub/extras

Produktdetaljer

ISBN
9783540461289
Publisert
2007-08-02
Utgiver
Vendor
Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Høyde
254 mm
Bredde
178 mm
Aldersnivå
Graduate, UU, 05
Språk
Product language
Engelsk
Format
Product format
Innbundet

Forfatter