Featuring new experiments, a new essay, and new coverage of nanotechnology, this organic chemistry laboratory textbook offers a comprehensive treatment of laboratory techniques including small scale and some microscale methods that use standard-scale ("macroscale") glassware and equipment. The book is organized based on essays and topics of current interest and covers a large number of traditional organic reactions and syntheses, as well as experiments with a biological or health science focus. Seven introductory technique-based experiments, thirteen project-based experiments, and sections on green chemistry and biofuels spark students' interest and engage them in the learning process. Instructors may choose to offer Cengage Learning's optional Premium Website, which contains videos on basic organic laboratory techniques.
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Featuring new experiments, a new essay, and new coverage of nanotechnology, this organic chemistry laboratory textbook offers a comprehensive treatment of laboratory techniques including small scale and some microscale methods that use standard-scale ("macroscale") glassware and equipment.
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Introduction.
WELCOME TO ORGANIC CHEMISTRY.
Laboratory Safety. Organization of the Textbook. Advance Preparation. Budgeting Time. Purpose.
PART I: INTRODUCTION TO BASIC LABORATORY TECHNIQUES.
Experiment 1. Solubility.
Experiment 2. Crystallization.
Experiment 3. Extraction.
Experiment 4. A Separation and Purification Scheme.
Experiment 4A. Extractions with a Separatory Funnel.
Experiment 4B. Extractions with a Screw-Cap Centrifuge Tube
Experiment 5. Chromatography.
Experiment 5A. Thin-Layer Chromatography.
Experiment 5B. Selecting the Correct Solvent for Thin-Layer Chromatography.
Experiment 5C. Monitoring a Reaction with Thin Layer Chromatography.
Experiment 5D. Column Chromatography.
Experiment 6. Simple and Fractional Distillation
Experiment 7. Infrared Spectroscopy and Boiling-Point Determination
Essay. Aspirin.
Experiment 8. Acetylsalicylic Acid.
Essay. Analgesics.
Experiment 9. Acetaminophen.
Essay. Identification of Drugs.
Experiment 10.TLC Analysis of Analgesic Drugs.
Essay. Caffeine.
Experiment 11. Isolation of Caffeine.
Experiment 11A. Extraction of Caffeine from Tea.
Experiment 11B. Isolation of Caffeine from a Tea Bag.
Essay. Esters--Flavors and Fragrances.
Experiment 12: Isopentyl Acetate (Banana Oil).
Essay, Terpenes and Phenylpropanoids.
Experiment 13. Isolation of Eugenol from Cloves.
Essay. Stereochemical Theory of Odor.
Experiment 14. Spearmint and Caraway Oil: (+)- and (-)- Carvones.
Essay.The Chemistry of Vision.
Experiment 15. Isolation of Chlorophyll and Carotenoid Pigments from Spinach.
Essay: Ethanol and Fermentation Chemistry.
Experiment 16. Ethanol from Sucrose.
PART II: INTRODUCTION TO MOLECULAR MODELING.
Essay: Molecular Modeling and Molecular Mechanics.
Experiment 17. An Introduction to Molecular Modeling.
Experiment 17A. The Conformations of n-Butane: Local Minima.
Experiment 17B. Cyclohexane Chair and Boat Conformations.
Experiment 17C. Substituted Cyclohexane Rings (Critical Thinking Exercise).
Experiment 17D. cis- and trans-2-Butene.
Essay: Computational Chemistry - Ab initio and Semiempirical Methods.
Experiment 18. Computational Chemistry.
Experiment 18A. Heats of Formation: Isomerism, Tautomerism, and Regioselectivity.
Experiment 18B. Heats of Reactions: SN1 Reaction Rates.
Experiment 18C. Density-Electrostatic Potential. Maps: Acidities of Carboxylic Acids.
Experiment 18D. Density -Electrostatic Potential Maps: Carbocations.
Experiment 18E. Density -LUMO Maps: Reactivities of Carbonyl Groups.
PART III: PREPARATIONS AND REACTIONS OF ORGANIC COMPOUNDS.
Experiment 19. Reactivities of Some Alkyl Halides.
Experiment 20. Nucleophilic Substitution Reactions: Competing Nucleophiles
Experiment 20A. Competing Nucleophiles with 1-Butanol or 2-Butanol.
Experiment 20B. Competing Nucleophiles with 2-Methyl-2-Propanol.
Experiment 20C. Analysis.
Experiment 21. Synthesis of n-Butyl Bromide and t-Pentyl Chloride.
Experiment 21A. n-Butyl Bromide.
Experiment 21B. t-Pentyl Chloride.
Experiment 22. 4-Methylcyclohexen
Essay. Fats and Oils.
Experiment 23. Methyl Stearate from Methyl Oleate.
Essay: Soap
Experiment 24. Preparation of Soap.
Essay: Petroleum and Fossil Fuels.
Experiment 25. Gas Chromatographic Analysis of Gasolines.
Essay: Biofuels.
Experiment 26. Biodiesel.
Experiment 26A. Biodiesel from Coconut Oil.
Experiment 26B. Biodiesel from Other Oils.
Experiment 26C. Analysis of Biodiesel.
Essay: Green Chemistry.
Experiment 27. Chiral Reduction of Ethyl Acetoacetate; Optical Purity Determination.
Experiment 27A. Chiral Reduction of Ethyl Acetoacetate.
Experiment 27B. NMR Determination of the Optical Purity of Ethyl (S)-3-Hydroxybutanoate.
Experiment 28. Nitration of Aromatic Compounds Using a Recyclable Catalyst.
Experiment 29. Reduction of Ketones Using Carrots as Biological Reducing Agents
Experiment 30. Resolution of (+/-)-alpha-Phenylethylamine and Determination of Optical Purity.
Experiment 30A. Resolution of (+/-)-alpha-Phenylethylamine.
Experiment 30B. Determination of Optical Purity Using NMR and a Ch
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Produktdetaljer
ISBN
9781305253926
Publisert
2015-02-11
Utgave
4. utgave
Utgiver
Vendor
Brooks/Cole
Vekt
2154 gr
Høyde
40 mm
Bredde
223 mm
Dybde
279 mm
Aldersnivå
U, 05
Språk
Product language
Engelsk
Format
Product format
Innbundet
Antall sider
1024